- silyl group
- Макаров: силильная группа
Универсальный англо-русский словарь. Академик.ру. 2011.
silyl group
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Silyl ether — General structure of a silyl ether Silyl ethers are a group of chemical compounds which contain a silicon atom covalently bonded to an alkoxy group. The general structure is R1R2R3Si−O−R4 where R4 is an alkyl group or an aryl group. Silyl ethers… … Wikipedia
Silyl enol ether — Silyl enol ethers in organic chemistry are a class of organic compounds sharing a common functional group composed of an enolate bonded through its oxygen terminus to an organosilicon group.Silyl enol ethers are important intermediates in organic … Wikipedia
Protecting group — A protecting group or protective group is introduced into a molecule by chemical modification of a functional group in order to obtain chemoselectivity in a subsequent chemical reaction. It plays an important role in multistep organic synthesis.… … Wikipedia
Danishefsky Taxol total synthesis — overview from raw material perspective The Danishefsky Taxol total synthesis in organic chemistry is an important third Taxol synthesis published by the group of Samuel Danishefsky in 1996 [1] two years after the first two efforts … Wikipedia
Silylation — is the introduction of a (usually) substituted silyl group (R3Si–) to a molecule. Nearly all functional groups which present a problem in gas chromatogaphic separation (hydroxyl, carboxylic acid, amine, thiol, phosphate) can be derivatized by… … Wikipedia
Tetrahedrane — is a platonic hydrocarbon with chemical formula carbon4hydrogen4 and a tetrahedral structure. Extreme angle strain (carbon bond angles deviate considerably from the tetrahedral bond angle of 109.5°) prevents this molecule from forming outside of… … Wikipedia
Tétra(triméthylsilyl) tétraèdrane — Tétraèdrane Le tétraèdrane est l hydrocarbure de Platon de formule C4H4 et de forme tétraédrique. Son nom IUPAC est tricyclo[1.1.0.02,4]butane. Les angles entre les liaisons carbone carbone dans le tétraèdrane (60°) sont considérablement plus… … Wikipédia en Français
Tétra(triméthylsilyl)tétraèdrane — Tétraèdrane Le tétraèdrane est l hydrocarbure de Platon de formule C4H4 et de forme tétraédrique. Son nom IUPAC est tricyclo[1.1.0.02,4]butane. Les angles entre les liaisons carbone carbone dans le tétraèdrane (60°) sont considérablement plus… … Wikipédia en Français
Tétraèdrane — Le tétraèdrane est l hydrocarbure de Platon de formule C4H4 et de forme tétraédrique. Son nom IUPAC est tricyclo[1.1.0.02,4]butane. Les angles entre les liaisons carbone carbone dans le tétraèdrane (60°) sont considérablement plus petits que de l … Wikipédia en Français
Nazarov cyclization reaction — The Nazarov cyclization reaction (often referred to as simply the Nazarov cyclization) is a chemical reaction used in organic chemistry for the synthesis of cyclopentenones. The reaction is typically divided into classical and modern variants,… … Wikipedia
Silanes — This article is about a class of chemical compounds. For the compound with chemical formula SiH4, see Silane. Silanes are chemical compounds of silicon and hydrogen, which are analogues of alkane hydrocarbons. Silanes consist of a chain of… … Wikipedia
